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Physical Properties and Regulating Mechanism of FluorideFree and Harmless B2O3Containing Mould Flux

LI Guirong , WANG Hongming , DAI Qixun , ZHAO Yutao , LI Jingsheng

钢铁研究学报(英文版)

The flux agents in common mould fluxes were fluoride and sodium oxide, which would do great harm to environments. B2O3 was selected as flux. The physical properties of B2O3containing mould fluxes were studied. The corresponding physical properties of 3791%CaO4309%SiO25%Al2O35%MgO2%Li2O7%B2O3 mould fluxes were as follows: the melting point was 909 ℃, the flowing temperature was 1 160 ℃, the viscosity and surface tension at 1 300 ℃ were 04 Pa·s and 032 N/m respectively, which could meet the demands for certain kinds of steels for mould fluxes in continuous casting.

关键词: B2O3containing mould flux;fluoridefree flux;harmless flux;physical property

Effect of Additives on Melting Point of LATS Refining Ladle Slag

WANG Hongming , LI Guirong , DING Zhentao , DAI Qixun , LI Bo

钢铁研究学报(英文版)

To avoid slag sticking on the ladle immersion cover during the LATS refining and alloying process, the effect of Al2O3 on the melting point of the ladle slag was studied and the additives including CaF2, B2O3, Li2O, and CaO were used to decrease the melting point of the ladle slag. The melting point was measured using the hemisphere method. The results show that the addition of Al2O3 to the ladle slag increases the melting point. The fluxing action is not remarkable if only CaF2 or CaO is used as the additive. The fluxing action of the composite additive obtained by the mixing of CaO and CaF2 in the mass proportion of wCaO∶wCaF2=2∶1 is preferred. The fluxing action of B2O3 is also notable. When the B2O3 content in mass percent is in the range from 2% to 10%, the corresponding melting point is 1 380 ℃ to 1 290 ℃. The fluxing action of Li2O is the most remarkable. When the Li2O content is up to 5%, the melting point of the slag is lower than 1 300 ℃.

关键词: LATS refining;ladle slag;melting point;additive;immersion cover

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